NMR: Novice Level, Spectrum 1

Formula: C4H8O2

Answer: Ethyl Acetate

Chemical Shift Assignments:

1H NMR: δ 1.24 (t, 3H), 2.02 (s, 3H), 4.10 (qt, 2H)

13C NMR: 170.8, 60.3, 20.8, 14.1 ppm

 

The signals at δ 1.24 (t, 3H) and 4.10 (qt, 2H) are a typical ethyl pattern. The chemical shift of the CH2 indicates it is attached to a heteroatom. The methyl singlet, δ 2.02 (s, 3H), is adjacent to a carbonyl group.

The signal at 170.8 ppm is weak (no hydrogens attached) and is in the range for an ester carbonyl. The signal at 60.3 ppm is a carbon attached to a heteroatom. The carbon of the methyl group attached to the carbonyl carbon is deshielded (20.8 ppm) relative to the methyl carbon at 14.1 ppm. The small triplet at 77.6 ppm is DCCl3. Return to Menu.

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