Entering Link 1 = C:\G03W\l1.exe PID=      3856.
  
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                  All Rights Reserved.
  
 This is the Gaussian(R) 03 program.  It is based on the
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 Carnegie Mellon University). Gaussian is a federally registered
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 Cite this work as:
 Gaussian 03, Revision B.05,
 M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, 
 M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, 
 K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, 
 V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, 
 G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, 
 R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, 
 H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, 
 C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, 
 A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, 
 K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, 
 V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, 
 O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, 
 J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, 
 J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, 
 I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, 
 C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, 
 B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople, 
 Gaussian, Inc., Pittsburgh PA, 2003.
 
 **********************************************
 Gaussian 03:  x86-Win32-G03RevB.05  8-Nov-2003
                  15-May-2009 
 **********************************************
 %chk=C:/Ziegler/formaldehyde.chk
 %mem=6MW
 %nproc=1
 Will use up to    1 processors via shared memory.
 Default route:  MaxDisk=2000MB
 ---------------------------------------
 # hf geom=connectivity pop=full gfprint
 ---------------------------------------
 1/38=1,57=2/1;
 2/17=6,18=5,40=1/2;
 3/11=9,16=1,24=100,25=1,30=1/1,2,3;
 4//1;
 5/5=2,32=1,38=5/2;
 6/7=3,28=1/1;
 99/5=1,9=1/99;
 ------------
 formaldehyde
 ------------
 Symbolic Z-matrix:
 Charge =  0 Multiplicity = 1
 C
 O                    1    B1
 H                    1    B2       2    A1
 H                    1    B3       2    A2       3    D1       0
       Variables:
  B1                    1.22465                  
  B2                    1.10217                  
  B3                    1.1012                   
  A1                  122.20829                  
  A2                  122.26483                  
  D1                 -180.                       
 
                          Input orientation:                          
 ---------------------------------------------------------------------
 Center     Atomic     Atomic              Coordinates (Angstroms)
 Number     Number      Type              X           Y           Z
 ---------------------------------------------------------------------
    1          6             0        0.000000    0.000000    0.000000
    2          8             0        0.000000    0.000000    1.224653
    3          1             0        0.932564    0.000000   -0.587456
    4          1             0       -0.931166    0.000000   -0.587859
 ---------------------------------------------------------------------
                    Distance matrix (angstroms):
                    1          2          3          4
     1  C    0.000000
     2  O    1.224653   0.000000
     3  H    1.102171   2.037992   0.000000
     4  H    1.101203   2.037711   1.863730   0.000000
 Stoichiometry    CH2O
 Framework group  CS[SG(CH2O)]
 Deg. of freedom     5
 Full point group                 CS      NOp   2
 Largest Abelian subgroup         CS      NOp   2
 Largest concise Abelian subgroup C1      NOp   1
                         Standard orientation:                         
 ---------------------------------------------------------------------
 Center     Atomic     Atomic              Coordinates (Angstroms)
 Number     Number      Type              X           Y           Z
 ---------------------------------------------------------------------
    1          6             0        0.000087   -0.538869    0.000000
    2          8             0        0.000087    0.685783    0.000000
    3          1             0       -0.932477   -1.126325    0.000000
    4          1             0        0.931253   -1.126728    0.000000
 ---------------------------------------------------------------------
 Rotational constants (GHZ):    288.7326317     37.7178326     33.3599436
 Standard basis: STO-3G (5D, 7F)
 AO basis set:
 Atom C1       Shell     1 S   3     bf    1 -     1          0.000165215191         -1.018315034875          0.000000000000
      0.7161683735D+02  0.1543289673D+00
      0.1304509632D+02  0.5353281423D+00
      0.3530512160D+01  0.4446345422D+00
 Atom C1       Shell     2 SP   3    bf    2 -     5          0.000165215191         -1.018315034875          0.000000000000
      0.2941249355D+01 -0.9996722919D-01  0.1559162750D+00
      0.6834830964D+00  0.3995128261D+00  0.6076837186D+00
      0.2222899159D+00  0.7001154689D+00  0.3919573931D+00
 Atom O2       Shell     3 S   3     bf    6 -     6          0.000165215191          1.295942818244          0.000000000000
      0.1307093214D+03  0.1543289673D+00
      0.2380886605D+02  0.5353281423D+00
      0.6443608313D+01  0.4446345422D+00
 Atom O2       Shell     4 SP   3    bf    7 -    10          0.000165215191          1.295942818244          0.000000000000
      0.5033151319D+01 -0.9996722919D-01  0.1559162750D+00
      0.1169596125D+01  0.3995128261D+00  0.6076837186D+00
      0.3803889600D+00  0.7001154689D+00  0.3919573931D+00
 Atom H3       Shell     5 S   3     bf   11 -    11         -1.762126142486         -2.128445256230          0.000000000000
      0.3425250914D+01  0.1543289673D+00
      0.6239137298D+00  0.5353281423D+00
      0.1688554040D+00  0.4446345422D+00
 Atom H4       Shell     6 S   3     bf   12 -    12          1.759813129809         -2.129207080475          0.000000000000
      0.3425250914D+01  0.1543289673D+00
      0.6239137298D+00  0.5353281423D+00
      0.1688554040D+00  0.4446345422D+00
 There are    10 symmetry adapted basis functions of A'  symmetry.
 There are     2 symmetry adapted basis functions of A"  symmetry.
 Integral buffers will be    262144 words long.
 Raffenetti 1 integral format.
 Two-electron integral symmetry is turned on.
    12 basis functions,    36 primitive gaussians,    12 cartesian basis functions
     8 alpha electrons        8 beta electrons
       nuclear repulsion energy        30.9437148561 Hartrees.
 NAtoms=    4 NActive=    4 NUniq=    4 SFac= 1.00D+00 NAtFMM=   60 Big=F
 One-electron integrals computed using PRISM.
 NBasis=    12 RedAO= T  NBF=    10     2
 NBsUse=    12 1.00D-06 NBFU=    10     2
 Harris functional with IExCor=  205 diagonalized for initial guess.
 ExpMin= 1.69D-01 ExpMax= 1.31D+02 ExpMxC= 1.31D+02 IAcc=1 IRadAn=         1 AccDes= 1.00D-06
 HarFok:  IExCor= 205 AccDes= 1.00D-06 IRadAn=         1 IDoV=1
 ScaDFX=  1.000000  1.000000  1.000000  1.000000
 Initial guess orbital symmetries:
       Occupied  (A') (A') (A') (A') (A') (A') (A") (A')
       Virtual   (A") (A') (A') (A')
 The electronic state of the initial guess is 1-A'.
 Warning!  Cutoffs for single-point calculations used.
 Requested convergence on RMS density matrix=1.00D-04 within 128 cycles.
 Requested convergence on MAX density matrix=1.00D-02.
 Requested convergence on             energy=5.00D-05.
 No special actions if energy rises.
 Keep R1 integrals in memory in canonical form, NReq=      422871.
 Convergence on energy, delta-E=-4.94D-05
 SCF Done:  E(RHF) =  -112.354192658     A.U. after    5 cycles
             Convg  =    0.2801D-03             -V/T =  2.0090
             S**2   =   0.0000

 **********************************************************************

            Population analysis using the SCF density.

 **********************************************************************

 Orbital symmetries:
       Occupied  (A') (A') (A') (A') (A') (A') (A") (A')
       Virtual   (A") (A') (A') (A')
 The electronic state is 1-A'.
 Alpha  occ. eigenvalues --  -20.31035 -11.12322  -1.33169  -0.80733  -0.63155
 Alpha  occ. eigenvalues --   -0.54242  -0.43842  -0.35481
 Alpha virt. eigenvalues --    0.27945   0.62563   0.73635   0.90055
     Molecular Orbital Coefficients
                           1         2         3         4         5
                        (A')--O   (A')--O   (A')--O   (A')--O   (A')--O
     EIGENVALUES --   -20.31035 -11.12322  -1.33169  -0.80733  -0.63155
   1 1   C  1S          0.00053   0.99263  -0.12158  -0.18619   0.00018
   2        2S         -0.00704   0.03286   0.27788   0.57920  -0.00069
   3        2PX         0.00000   0.00001   0.00002   0.00050   0.53331
   4        2PY        -0.00620   0.00051   0.15642  -0.22283  -0.00027
   5        2PZ         0.00000   0.00000   0.00000   0.00000   0.00000
   6 2   O  1S          0.99430   0.00015  -0.21959   0.09923  -0.00018
   7        2S          0.02578  -0.00568   0.77173  -0.43125   0.00087
   8        2PX         0.00000   0.00000   0.00001   0.00017   0.43557
   9        2PY        -0.00551   0.00171  -0.16710  -0.16500   0.00076
  10        2PZ         0.00000   0.00000   0.00000   0.00000   0.00000
  11 3   H  1S          0.00019  -0.00651   0.03191   0.26405  -0.30419
  12 4   H  1S          0.00019  -0.00652   0.03197   0.26488   0.30379
                           6         7         8         9        10
                        (A')--O   (A")--O   (A')--O   (A")--V   (A')--V
     EIGENVALUES --    -0.54242  -0.43842  -0.35481   0.27945   0.62563
   1 1   C  1S          0.03251   0.00000  -0.00002   0.00000  -0.20761
   2        2S         -0.10736   0.00000   0.00022   0.00000   1.29688
   3        2PX        -0.00050   0.00000  -0.17905   0.00000  -0.00440
   4        2PY        -0.45057   0.00000  -0.00017   0.00000  -0.44638
   5        2PZ         0.00000   0.61064   0.00000   0.81922   0.00000
   6 2   O  1S         -0.09303   0.00000   0.00000   0.00000   0.02718
   7        2S          0.49434   0.00000  -0.00001   0.00000  -0.15530
   8        2PX        -0.00069   0.00000   0.87456   0.00000   0.00128
   9        2PY         0.67526   0.00000   0.00024   0.00000   0.24114
  10        2PZ         0.00000   0.67641   0.00000  -0.76582   0.00000
  11 3   H  1S          0.16062   0.00000   0.35353   0.00000  -0.89184
  12 4   H  1S          0.16033   0.00000  -0.35308   0.00000  -0.88619
                          11        12
                        (A')--V   (A')--V
     EIGENVALUES --     0.73635   0.90055
   1 1   C  1S         -0.00103  -0.09568
   2        2S          0.00703   0.62691
   3        2PX         1.15059  -0.00219
   4        2PY        -0.00021   1.16116
   5        2PZ         0.00000   0.00000
   6 2   O  1S          0.00032   0.11490
   7        2S         -0.00211  -0.84873
   8        2PX        -0.31217   0.00052
   9        2PY         0.00265   0.92110
  10        2PZ         0.00000   0.00000
  11 3   H  1S          0.83794   0.14626
  12 4   H  1S         -0.84509   0.14991
      DENSITY MATRIX.
                           1         2         3         4         5
   1 1   C  1S          2.07164
   2        2S         -0.22500   0.85069
   3        2PX        -0.00001  -0.00012   0.63297
   4        2PY         0.01665  -0.07432   0.00001   0.55435
   5        2PZ         0.00000   0.00000   0.00000   0.00000   0.74575
   6 2   O  1S          0.01175  -0.00109  -0.00001  -0.04143   0.00000
   7        2S         -0.00617  -0.17755   0.00004  -0.01219   0.00000
   8        2PX         0.00001   0.00014   0.15141   0.00002   0.00000
   9        2PY         0.14937  -0.42881  -0.00012  -0.58719   0.00000
  10        2PZ         0.00000   0.00000   0.00000   0.00000   0.82608
  11 3   H  1S         -0.10870   0.28927  -0.45095  -0.25240   0.00000
  12 4   H  1S         -0.10880   0.28917   0.45058  -0.25258   0.00000
                           6         7         8         9        10
   6 2   O  1S          2.11072
   7        2S         -0.46523   2.05321
   8        2PX         0.00001  -0.00007   1.90914
   9        2PY        -0.09595   0.55172   0.00010   1.02233
  10        2PZ         0.00000   0.00000   0.00000   0.00000   0.91505
  11 3   H  1S          0.00900  -0.02015   0.35324   0.11880   0.00000
  12 4   H  1S          0.00897  -0.01998  -0.35306   0.11871   0.00000
                          11        12
  11 3   H  1S          0.62819
  12 4   H  1S         -0.24095   0.62778
    Full Mulliken population analysis:
                           1         2         3         4         5
   1 1   C  1S          2.07164
   2        2S         -0.05588   0.85069
   3        2PX         0.00000   0.00000   0.63297
   4        2PY         0.00000   0.00000   0.00000   0.55435
   5        2PZ         0.00000   0.00000   0.00000   0.00000   0.74575
   6 2   O  1S          0.00000  -0.00004   0.00000  -0.00249   0.00000
   7        2S         -0.00022  -0.06335   0.00000  -0.00532   0.00000
   8        2PX         0.00000   0.00000   0.03109   0.00000   0.00000
   9        2PY        -0.00876   0.13624   0.00000   0.18394   0.00000
  10        2PZ         0.00000   0.00000   0.00000   0.00000   0.16960
  11 3   H  1S         -0.00658   0.13994   0.17668   0.06229   0.00000
  12 4   H  1S         -0.00660   0.14005   0.17656   0.06248   0.00000
                           6         7         8         9        10
   6 2   O  1S          2.11072
   7        2S         -0.11012   2.05321
   8        2PX         0.00000   0.00000   1.90914
   9        2PY         0.00000   0.00000   0.00000   1.02233
  10        2PZ         0.00000   0.00000   0.00000   0.00000   0.91505
  11 3   H  1S          0.00004  -0.00141  -0.01268  -0.00828   0.00000
  12 4   H  1S          0.00004  -0.00140  -0.01266  -0.00829   0.00000
                          11        12
  11 3   H  1S          0.62819
  12 4   H  1S         -0.03578   0.62778
     Gross orbital populations:
                           1
   1 1   C  1S          1.99360
   2        2S          1.14765
   3        2PX         1.01729
   4        2PY         0.85525
   5        2PZ         0.91535
   6 2   O  1S          1.99815
   7        2S          1.87138
   8        2PX         1.91489
   9        2PY         1.31718
  10        2PZ         1.08465
  11 3   H  1S          0.94241
  12 4   H  1S          0.94219
          Condensed to atoms (all electrons):
              1          2          3          4
     1  C    4.743633   0.440684   0.372338   0.372494
     2  O    0.440684   7.790204  -0.022333  -0.022306
     3  H    0.372338  -0.022333   0.628186  -0.035778
     4  H    0.372494  -0.022306  -0.035778   0.627780
 Mulliken atomic charges:
              1
     1  C    0.070850
     2  O   -0.186249
     3  H    0.057588
     4  H    0.057811
 Sum of Mulliken charges=   0.00000
 Atomic charges with hydrogens summed into heavy atoms:
              1
     1  C    0.186249
     2  O   -0.186249
     3  H    0.000000
     4  H    0.000000
 Sum of Mulliken charges=   0.00000
 Electronic spatial extent (au):  <R**2>=    58.9040
 Charge=     0.0000 electrons
 Dipole moment (field-independent basis, Debye):
    X=     0.0007    Y=    -1.5472    Z=     0.0000  Tot=     1.5472
 Quadrupole moment (field-independent basis, Debye-Ang):
   XX=   -10.5212   YY=   -11.3029   ZZ=   -10.4306
   XY=    -0.0006   XZ=     0.0000   YZ=     0.0000
 Traceless Quadrupole moment (field-independent basis, Debye-Ang):
   XX=     0.2304   YY=    -0.5513   ZZ=     0.3210
   XY=    -0.0006   XZ=     0.0000   YZ=     0.0000
 Octapole moment (field-independent basis, Debye-Ang**2):
  XXX=    -0.0003  YYY=     2.7097  ZZZ=     0.0000  XYY=     0.0009
  XXY=     0.4387  XXZ=     0.0000  XZZ=     0.0005  YZZ=     1.6315
  YYZ=     0.0000  XYZ=     0.0000
 Hexadecapole moment (field-independent basis, Debye-Ang**3):
 XXXX=   -14.5933 YYYY=   -40.1251 ZZZZ=    -6.8897 XXXY=    -0.0013
 XXXZ=     0.0000 YYYX=    -0.0041 YYYZ=     0.0000 ZZZX=     0.0000
 ZZZY=     0.0000 XXYY=    -8.3062 XXZZ=    -3.8169 YYZZ=    -7.7401
 XXYZ=     0.0000 YYXZ=     0.0000 ZZXY=    -0.0011
 N-N= 3.094371485613D+01 E-N=-3.268672031955D+02  KE= 1.113502776800D+02
 Symmetry A'   KE= 1.077806080264D+02
 Symmetry A"   KE= 3.569669653574D+00
 Orbital energies and kinetic energies (alpha):
                           1         2
       1  (A')--O     -20.31035  28.66577
       2  (A')--O     -11.12322  15.65316
       3  (A')--O      -1.33169   2.43885
       4  (A')--O      -0.80733   1.54156
       5  (A')--O      -0.63155   1.22279
       6  (A')--O      -0.54242   2.16570
       7  (A")--O      -0.43842   1.78483
       8  (A')--O      -0.35481   2.20247
       9  (A")--V       0.27945   2.35804
      10  (A')--V       0.62563   2.47058
      11  (A')--V       0.73635   2.38777
      12  (A')--V       0.90055   3.95875
 Total kinetic energy from orbitals= 1.113502776800D+02
 1|1|UNPC-UNK|SP|RHF|STO-3G|C1H2O1|PCUSER|15-May-2009|0||# HF GEOM=CONN
 ECTIVITY POP=FULL GFPRINT||formaldehyde||0,1|C|O,1,1.22465251|H,1,1.10
 217081,2,122.20828986|H,1,1.10120263,2,122.26483047,3,-180.,0||Version
 =x86-Win32-G03RevB.05|State=1-A'|HF=-112.3541927|RMSD=2.801e-004|Dipol
 e=-0.0002568,0.,-0.6087325|PG=CS [SG(C1H2O1)]||@


 WHEN ALL ELSE FAILS, TRY THE BOSS'S SUGGESTION.
 Job cpu time:  0 days  0 hours  0 minutes  2.0 seconds.
 File lengths (MBytes):  RWF=     11 Int=      0 D2E=      0 Chk=      7 Scr=      1
 Normal termination of Gaussian 03 at Fri May 15 13:32:15 2009.