The prevailing theory of organic structure in the early 19th century was Dualism or the Electrochemical Theory, principally championed by Berzelius. Since inorganic sodium chloride could be considered as Na⁺Cl^-, then an alkyl halide such as RCl could be thought of as R⁺Cl^-. The R group or "radical" of its day, was thought to be immutable, the carbons and hydrogens behaving as though they were an element. Liebig (German) and Dumas (French), influential chemists of the day, published a joint paper (1837), On the Present State of Organic Chemistry, extolling the concept and claiming all that was left to do in organic chemistry was to identify these immutable radicals (benzoyl, ethyl, acetyl, etc.) As the story goes, a Parisian reception at the Tuileries was to change all of this. [The Tuilerie Gardens was one of the images in Mussorgsky's "Pictures at an an Exhibition", composed in 1874 for piano and later orchestrated by Ravel. The Tuileries selection is here. For the history of this composition and background music, go here. (At Yale, try this.] The guests were discomforted by fumes from the burning candles. Dumas was called in as a consultant. He found that the waxes (fatty esters) had exchanged chlorine for hydrogen, the culprit being the by-product hydrogen chloride. [This story is likely apocryphal. It was told by August Hofmann at a eulogy for Dumas (1884). If the event did occur, it is more likely that the bleaching of candle wax involved addition of chlorine to double bonds. Nonetheless, Dumas did investigate substitution reactions.]